Index
Chapter 1 · Item 1.10
Bohr model: hydrogen spectrum
Energy levels, radii and the Rydberg formula
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Guided reading

This topic follows the consequences of Bohr's postulates. Combining Coulomb attraction with angular-momentum quantization gives \(r_n=a_0n^2\), so atomic radii are no longer arbitrary. Substituting the allowed radii into the mechanical energy gives \(E_n=-E_0/n^2\).

Now the Hydrogen spectrum becomes quantitative: a transition from \(m\) to \(n\) emits a photon with \(hc/\lambda=E_m-E_n\), which reproduces the Rydberg formula. The empirical integers in spectroscopy are now explained as energy-level labels.

Energy ladder
Fig. 1.9, adapted from the original chapter: Bohr energy levels organize the Hydrogen spectral series.
Fig. 1.9, adapted from the original chapter: Bohr energy levels organize the Hydrogen spectral series. Copyright © 2026 Elsevier Inc.

Hydrogen levels become a ladder of bound states. The ground state is the most tightly bound, and higher \(n\) levels approach the ionization limit \(E=0\).

Spectral lines arise when the atom moves between two rungs of this ladder.

Radii and energy

Combining \(mvr=n\hbar\) with \(mv^2=\kappa e^2/r\) gives the allowed radii:

\[r_n=a_0n^2,\qquad a_0=0.529\ \text{\AA}\]

Substituting these radii into \(E=-\kappa e^2/(2r)\) gives the energy spectrum:

\[E_n=-\frac{E_0}{n^2},\qquad E_0=13.6\ \mathrm{eV}\]

The radius grows as \(n^2\), while the energy approaches zero from below as \(n\) increases.

Recovering Rydberg

For a transition from \(m\) to \(n\), the photon energy is

\[hf=\frac{hc}{\lambda}=E_m-E_n.\]
\[\frac{1}{\lambda}=\frac{E_0}{hc}\left(\frac{1}{n^2}-\frac{1}{m^2}\right)\]
\[R=\frac{E_0}{hc}=1.097\times 10^7\ \mathrm{m^{-1}}\]

What was empirical in Rydberg's formula becomes a consequence of energy quantization.

Conceptual discussion

The success is real but narrow. Bohr explains Hydrogen-like spectra and the Rydberg constant, but not the general structure of quantum states, spin, multi-electron atoms or measurement. The model is a bridge toward wave mechanics.

Reasoning bridge for spectrum exercises

To use the Bohr model in an exercise, keep the calculation chain visible. The Coulomb force supplies the centripetal force, while angular momentum quantization selects only certain radii:

\[\frac{m_ev^2}{r}=\frac{e^2}{4\pi\varepsilon_0r^2},\qquad m_evr=n\hbar.\]

Solving these two relations gives the allowed radii and energies. The spectral line then comes from an energy difference, not from a continuous orbital frequency:

\[hf=E_i-E_f,\qquad \frac{1}{\lambda}=R_H\left(\frac{1}{n_f^2}-\frac{1}{n_i^2}\right).\]

This is enough scaffolding for short exercises on spectral series; detailed historical development and longer numerical examples belong in the book.

Exercise-ready boundary

This page is designed to support short guided exercises on: Energy levels, orbital radii and how the Bohr model explains Hydrogen spectral series.

  • Use from this page: the definitions, physical setup, highlighted equations and conceptual links needed to start a first calculation or explanation.
  • Keep in the book: complete derivations, extended historical discussion, worked solutions and the full textbook narrative remain in the original chapter and linked book resources.
  • Good exercise balance: ask the student to identify assumptions, apply one relation, and interpret the result physically, without requiring material not introduced on this page.
Practice anchors

Use these anchors to design compact exercises. The exercise should be answerable from this page plus standard algebra, while longer derivations, full worked examples and broader context should point back to the original book.

  • Focus: Energy levels, orbital radii and how the Bohr model explains Hydrogen spectral series.
  • Conceptual check: state what the main result says physically before using it algebraically.
  • Equation: \[r_n=a_0n^2,\qquad a_0=0.529\ \text{\AA}\]
  • Equation: \[E_n=-\frac{E_0}{n^2},\qquad E_0=13.6\ \mathrm{eV}\]
  • Equation: \[hf=\frac{hc}{\lambda}=E_m-E_n.\]
  • Boundary: use this page for setup and first-step reasoning; cite the book for longer derivations, complete experimental history or solved-problem detail.
  • Typical task: derive, interpret, or apply the relation above to a simple case without introducing topics outside this page.
Source note: Original auxiliary summary for this book-app, based on Chapter 1 of Mario Reis, Quantum Mechanics, Elsevier, 2026. Book text and figures are copyright © 2026 Elsevier Inc. Selected figure material is reproduced/adapted from Chapter 1 of the original book and carries a visible copyright watermark and caption.